|
Foreward (260kb) |
Disclaimer |
ii |
| |
Abstract |
iii |
| LIST OF TABLES |
vi |
| LIST OF FIGURES |
vii |
| Introduction |
ix |
| Executive Summary |
x |
| Experimental |
xii |
| Results and Discussion |
xii |
| Conclusions |
xii |
| Technical Discussion |
1 |
| Objectives |
3 |
| Scope of Work for Year 1 |
6 |
| Tasks to be Performed |
7 |
|
Section 1 (357kb) |
Task 1. Pilot-Scale Fuel Production at PARC |
8 |
| |
|
Subtask 1.1 LCO Procurement |
8 |
| Subtask 1.2 Catalyst Preparation |
9 |
| Subtask 1.3 Hydrotreatment of Blended Product |
10 |
| Subtask 1.4 Fractionation into Refinery Product
Slate |
10 |
| |
|
Parametric Study for Coal-Tar Processing Approach |
11 |
| Decant Oil Hydrotreating for Co-coking Approach |
13 |
|
Section 2 (339kb) |
Task 2. Evaluation of Coal-Based Gasoline and DIesel
Products in IC Engines and Related Studies |
19 |
| |
|
Subtask 2.1 Impact on Gasoline Quality and
Performance |
20 |
| |
2.1.1 |
Preparation of Laboratory Instrumentation |
21 |
|
2.1.2 |
Impact on Chemical and Physical Properties |
24 |
|
2.1.3 |
Impact on SI Engine Emissions and Performance |
24 |
| Subtask 2.2 Impact on Diesel Fuel
Quality and Performance |
24 |
| |
2.2.1 |
Acquisition, Installation and Instrumentation of
Ignition Test Equipment |
25 |
|
2.2.2 |
Development of Analytical Methods and Test
Procedures |
27 |
|
2.2.3 |
Evaluation of Capabilities and Needs for
Supplemental Measurements and Analyses |
27 |
|
2.2.4 |
Impact on Chemical and Physical Properties |
27 |
|
2.2.5 |
Impact on CI Engine Emissions and Performance |
28 |
|
Section 3 (585kb) |
Task 3. Desulfurization, Denitrogenation,
Saturation of Aromatics, Chemicals from Coal |
29 |
| |
|
Subtask 3.1 Desulfurization and
Denitrogenation |
30 |
| |
3.1.1 |
Experimental |
31 |
|
3.1.2 |
Results and Discussion |
33 |
|
3.1.2.1 |
The Effect of Nitrogen Compound on 4, 6-DMDBT HDS |
33 |
|
3.1.2.2 |
NiMo Supported on Mesoporous Support MCM-41 |
37 |
|
3.1.3 |
Summary |
40 |
|
3.1.4 |
Future Work |
41 |
|
3.1.4.1 |
Development of Deep Hydrodesulfurization Catalysts |
41 |
|
3.1.4.2 |
Adsorptive Denitrogenation of Model Feed for Deep
Hydrodesulfurization |
41 |
| Subtask 3.2 Saturation of Two-Ring
Aromatics |
41 |
| |
3.2.1 |
Experimental |
42 |
|
3.2.1.1 |
Catalyst Preparation |
42 |
|
3.2.1.2 |
Experimental |
43 |
|
3.2.2 |
Results and Discussion |
44 |
|
3.2.3 |
Summary |
46 |
|
3.2.4 |
Future work |
47 |
| |
Subtask 3.3 Value-Added Chemicals from Naphthalene
and Biphenyl |
47 |
|
3.3.1 |
Experimental |
48 |
|
3.3.1.1 |
Catalysts |
48 |
|
3.3.1.2 |
Catalyst Evaluation |
49 |
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3.3.2 |
Results and Discussion |
50 |
|
3.3.2.1 |
Types of Zeolites on the Methylation of 2-MN |
50 |
|
3.3.2.2 |
SiO2/Al2O3 Ratio of
HZSM-5 on the Methylation of 2-MN |
52 |
|
3.3.3 |
Summary |
54 |
|
3.3.4 |
Future Work |
54 |
|
Section 4 (3.55mb) |
Task 4. Evaluation of Coal-Based Fuel
Oil Products |
55 |
| |
|
Subtask 4.1 Fuel Analysis |
55 |
| Subtask 4.2 Fuel Atomization |
56 |
| Subtask 4.3 Watertube Boiler Combustion
Tests |
56 |
| |
4.3.1 |
Combustion Testing |
- |
|
4.3.2 |
Determination of Metals Emissions and Form of
Mercury from Stationary Sources |
- |
| Task 5. Pitch and Coal Material |
57 |
| |
Subtask 5.1 Sample Procurement and
Preparation |
58 |
| Subtask 5.2 Examine Resid from
Fractionation of Deeply HDT RCO/LCO as a Pitch Material |
64 |
| Subtask 5.3 Co-coking Coal and Heavy
Petroleum Stream |
65 |
| Subtask 5.4 Analysis of Co-coking Coke |
65 |
| Subtask 5.5 Distillation and Analysis of
Co-coking Binder Pitch |
65 |
| Subtask 5.6 Manufacture and Testing of
Carbon Artifacts |
65 |
| References |
67 |
| List of Acronyms and Abbreviations |
75 |
