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A Study of Industrial Hydrogen and Syngas Supply Systems - 1979

Amos, W. J.
Solomon, J.
Eliezer, K. F.
Rux, G. V.
Drissel, G. M.

Air Products and Chemicals, Inc.

Table of Contents 311kb

Section 1
979kb
1.0

Summary

1
2.0

Introduction

11
  2.1

Objective

11
2.2

JPL Energy Scenario

11
2.3  

Basic Assumptions

12

3.0

Task I Economic Assessment

14
 

3.1

Future Chemical Industry H2/CO/Syngas Capacity Requirements 1978-1987

14
 

3.1.1

Major Requirements Plants

18
 

3.1.1.1

Ammonia

18

3.1.1.2

Methanol

19

3.1.1.3

Benzene

22

3.1.1.4

Ethanol

25
Section 2
646kb

3.1.2

Oxo Alcohols

27
 

3.1.2.1

Solvent Alcohols

27

3.1.2.2

Plasticizer Alcohols

28

3.1.2.3

Detergent Alcohols

28

3.1.3

Polyurethanes and Aniline

34
 

3.1.3.1

MDI

34

3.1.3.2

TDI

35

3.1.3.3

Aniline

38

3.1.3.4

Supply/Demand Balances and H2/CO Requirements

39

3.1.4

Fibers

41
  3.1.4.1  

General Overview of U.S. Fibers Markets

41
 

3.1.4.1.1  U.S. Fiber Consumption

43

3.1.4.1.2  Summary of Statistical Data

46
3.1.4.2  

Ethylene Glycol

47
Section 3
682kb
3.1.4.3  

DMT/TPA

51
 

3.1.4.3.1  Markets

51

3.1.4.3.2  Polyethylene Terephthalate (PET) Film

51

3.1.4.3.3  Polybutylene Terephthalate (PBT) Resins

52

3.1.4.3.4  Polyethylene Terephthalate (PET) Barrier Resins

52

3.1.4.3.5  Supply/Demand Balances

53
3.1.4.4  

Acetic Anhydride

55

3.1.4.4.1  Markets and Supply/Demand Balance

55
3.1.4.5  

Hexamethylenediamine, Adipic Acid and Cyclohexane

55
 

3.1.4.5.1  HMDA

55

3.1.4.5.2  Adipic Acid/Caprolactam

57
3.1.5  

Other Chemicals

59
  3.1.5.1  

Acetic Acid

59
3.1.5.2  

Pesticides

61
 

3.1.5.2.1  Insecticides

61

3.1.5.2.2  Herbicides

61

3.1.5.2.3  Fungicides and Fumigants

64

3.1.5.2.4  Projected CO Requirements

64
3.1.5.3  

Polycarbonates

64
3.1.5.4  

Hydrogen Peroxide

67
3.1.5.5  

Butanediol

69
3.1.5.6  

Specialty Chemicals

69
 

3.1.5.6.1  Specific Chemicals

71

3.1.5.6.2  H2/CO Requirements

74
3.1.6  

Electrolytic Hydrogen Potential

74
Section 4
801kb
3.2  

Future Chemical Industry H2/CO/Syngas Capacity Requirements, 1988-2000

75
  3.2.1  

Major Requirements Plants

77
3.2.2  

Oxo Alcohols

78
3.2.3  

Polyurethanes

78
3.2.4  

Fibers

78
3.2.5  

Other Chemicals

79
3.3  

Economic Comparison of H2 and Syngas Production Costs using Coal Gasification Technology vs. Existing Production Methods

80
  3.3.1  

Methodology

81
  3.3.1.1  

Capital Cost Estimates

81
3.3.1.2  

Major Operating Cost Estimates

84
3.3.2  

Discussion of Results

85
  3.3.2.1  

Results for H2 and Syngas Production

86
3.3.2.2  

Pressurized vs. Atmospheric Gasification

97
3.3.2.3  

Evaluation of Co-Producing Fuel and Syngas

97
3.3.3  

Discussion of Revised Energy Scenario Sensitivity Cases

97
Section 5
668kb
  3.3.3.1  

Results for H2 and Syngas Production Using Revised Energy Scenario

102
3.3.3.2  

Revised Scenario Results for Pressurized vs. Atmospheric Gasification

113
3.3.3.3

  Revised Scenario Results for Co-Producing Fuel and Syngas

113
4.0  

Task II Analysis of Technical/Non-Technical Problem Areas

116
  4.1  

Analysis of Potential R&D Impact

116
  4.1.1  

Analysis of Potential R&D Impact Under Original Energy Scenario

116
4.1.2  

Analysis of Potential R&D Impact Under Revised Energy Scenario

121
Section 6
912kb
4.2  

Analysis of Institutional Barriers

126
  4.2.1  

Financing Considerations

126
4.2.2  

Technology and Cost Risk Factors In Coal Gasification

127
4.2.3  

Financing Techniques

128
4.3  

Analysis of Regulatory Barriers Affecting Coal Gasification

133
  4.3.1  

Impact of State Implementation Plan Delays on Commercial Potential

133
4.3.2  

Regulatory Barriers Affecting Coal Directly: Transporting/Mining

134
4.3.3  

Impact of Future Oil and Gas Regulatory Pricing Uncertainty

136
4.4  

Estimate of Government Incentives to Make Coal Gasification Competitive and Recommended Actions to Stimulate Coal Gasification System Development

138
  4.4.1  

Financial Incentives

138
4.4.2  

Recommended Options to Stimulate Coal Gasification System Development

141
4.4.3 

 Regulatory Actions

143

Appendix A: Description of Financial Analysis Computer Program