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6. Operating Conditions.

The main variables of the operation, such as pressure, temperature, space-velocity, gas composition are today practically the same, as in 1937-1938. Specifically, there was no improvement or change in the design of the ovens. Nevertheless there was no increase in the average yield expressed in gram/m3 feed gas from approximately 100 g to 130 g/m3. As Germany was faced with a serious lack of cobalt, the yield of product per ton of cobalt was of greatest importance, since this yield can be raised by keeping the space-velocity low, most plants were operated at less than 100 V/H/V (Vol feed gas/hr/unit volume catalyst).

The Essener Steinkohlen A.G. apparently had developed a somewhat improved method of operation, which resulted in a better yield based on feed, and longer catalyst life. This operation widely discussed by the FT group, was known as the “Essener Fahrweise”.

In principle, it consisted only in a rigorous control of operation, i.e.;

  1. Absolute constant feedgas rate and composition
  2. Countercurrent regeneration of all ovens.
  3. Low-space velocity (increased number of ovens).
  4. More equal distribution of load between stages.

With these means the Essener plant obtained the following results:

Essener

Others

Yield

160

130 C3+gm/m3 gas.

Catalyst life

2000

1400 hours

Catalyst yield

425

250 ton/ton catalyst

Flexibility of Operation. In order to show the variations possible in FT plant operation, yields and product qualities for 2 conditions listed below. The data are based on a report from Brabag and refer to their Ruhland Plant:

Processing

Case I

Case II

Absorber gasoline

160°C EP

140°C EP

Diesel oil

160-300°C Max

under 325°C

Gatsch

over 325°C

over 325°C

Yield

Gasol

5100 ton/year

7600 ton/year

Gasoline

73800 ton/year

83900 ton/year

Diesel oil

52500 ton/year

35100 ton/year

Gatsch

10100 ton/year

10100 ton/year

Products

Gasoline:

sp.gr.

0.686

0.689

Octane No.

56

62

Diesel oil:

sp.gr.

0.757

0.732

Pourpoint

-20°C

-60°C

Flashpoint

+56°C

+25°C

Vis E/20

1.08

1.022

Cetane No.

100

88

The difference is due to a variation in the amount of thermal cracking of the distillation fraction carried out in a separate unit.

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