| II |
Introduction |
3 |
| |
A |
Heterogenous Catalysis of CO Reduction |
3 |
|
B |
Homogenous Catalysis of CO Reduction |
4 |
| III |
Progress |
6 |
| |
A |
Synthesis and Reactivity Studies of
Ketene Clusters |
6 |
| |
1 |
Insertion of CO into the Os-(u-CH2) bond
of Os3(CO)11(u-CH2) |
6 |
|
2 |
Insertion of CO into the Os-methylene Bonds of (OS2(CO)10(U-CH2)(u-X)(X=C1.I.NCO) |
8 |
|
3 |
Reaction of Re(CO)5Br with [Cp(CO)(PPh3)FeC(O)CH21 |
9 |
|
B |
Divertive Chemistry of OS3(CO)11(u-CH2) |
10 |
|
C |
Formyl, Acyl, Carbene, and Hydride
Complexes Derived from the Nitrene-Bridged Cluster Fe3(u-NPh)2(CO)9
- Carbene-Nitrene Coupling |
12 |
|
D |
Binuclear Formyl and Acyl Complexes |
14 |
| |
| V |
References |
19 |
| |
Figure 1 |
6 |
| Figure 2 |
11 |
| Figure 3 |
13 |
| Figure 4 |
14 |
| Figure 5 |
15 |
| Figure 7 |
17 |
| |
| Table I. Vibrational Frequencies of the
u-CH2CO ligand in 2 |
7 |
